Special Analytics

GCxGC

Quantification of Middle Distillates

ASG 2253 GC×GC-TOFMS | ASG 2502 GC×GC-FID

ASG Analytik-Service gcxgc struktur 02
Principle of comprehensive two-dimensional gas chromatography

Comprehensive two-dimensional gas chromatography (GC×GC) provides the possibility of a detailed separation of complex fuel samples and their subdivision into different substance classes and individual components.

ASG can rely on many years of expertise in this field and provides various established methods for the analysis of middle distillates and higher boiling samples.

Detailed quantification of middle distillates of fossil origin (jet fuel, diesel, heating oil) as well as for sustainable fuels (e.g. HVO, SAF) can be provided using GC×GC–FID. Our in-house method ASG 2502 is based on ASTM D8396.

For higher boiling samples, the HT-GC×GC–FID according to our in-house standard ASG 2501 is also available.

Even more information can be obtained using GC×GC – ToFMS. Time-of-flight mass spectrometry enables rapid acquisition of mass spectra over a broad mass range. The subsequent script-based data processing allows an automated assignment of detected mass spectra to the corresponding substance classes. We provide a method for the boiling range of middle distillates (ASG 2253) as well as for higher boiling samples (ASG 2221).

Example of a 2D Chromatogram

In the following figures representative two-dimensional chromatograms of a conventional diesel fuel according to EN 590 are displayed along with the results of data analysis and quantification. The separation was achieved using a “reverse phase column combination” consisting of a 50% phenyl-substituted column as first dimension and a 100% polydimethylsiloxane column as second dimension.
ASG Analytik-Service 2D Chromatogramm Diesel EN 590
2D Chromatogram of a Diesel fuel
according to EN 590 before and …
ASG Analytik-Service 2D Chromatogramm von Diesel EN 590 nach der Datenverarbeitung
... after data evaluation
Quantifizierung des Dieselkraftstoff EN 590
Quantitative Results

Need help selecting the right GC method?

Gasoline / Naphtha

Carbon number: C5 - C12
Boiling range 35°C - 210°C

PIONA and
relevant Oxygenates

ASTM D8071
GC-VUV

prEN 18015
GC-VUV, Alternative for EN 22854 (Reformulyzer)

ASTM D8369
GC-VUV (VHA) 

Middle Distillates

Carbon number: C10 - C22
Boiling range 170°C - 370°C

Group Type Analysis for
Heating Oil, Diesel, Jet A1, SAF

ASG 2502
GC×GC-FID

ASG 2253
GC×GC-MS

Aromatics in Jet Fuel and SAF

ASTM D8267
GC-VUV

Mono- and di-aromatics as sum parameters, Alternative to ASTM D6379

Matrices with higher final boiling point

Carbon number: C17 - C55
Boiling range 300°C - 600°C

Hydrocarbon Group Type Analysis

ASG 2501
HT-GC×GC-FID

ASG 2221
HT-GC×GC-MS Screening

Process Oil from Waste Plastic (WPPO)

Carbon number: C5 - C64
Boiling range 35°C - 630°C

Hydrocarbon Group Type Analysis

ASTM D8519
GC-VUV

Contact
Dr. Max Jennerwein
Dr. Max Jennerwein
Head of R&D
Contact
Michael Becker
Michael Becker
Associate Scientist

Need additional analyses?

Our laboratory has been accredited since 1998 for the analysis of numerous fossil and biogenic fuels.